2-Azabicyclo[2.2.1]hept-5-enes from 7-azabicyclo[2.2.1]heptadienes by tandem intermolecular radical addition - Homoallylic radical rearrangement

D. M. Hodgson; M. W.P. Bebbington; P. Willis

doi:10.1039/b101984h

2-Azabicyclo[2.2.1]hept-5-enes from 7-azabicyclo[2.2.1]heptadienes by tandem intermolecular radical addition - Homoallylic radical rearrangement

D. M. Hodgson, M. W.P. Bebbington, P. Willis

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Addition of thiols to 7-azabicyclo[2.2.1]heptadienes such as 16 leads exclusively to 7-thio-substituted 2-azabicyclo[2.2.1]hept-5-enes 17 in good yields via tandem intermolecular radical addition - homoallylic radical rearrangement.

Original language	English
Pages (from-to)	889-890
Number of pages	2
Journal	Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/b101984h
State	Published - 21 May 2001

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title = "2-Azabicyclo[2.2.1]hept-5-enes from 7-azabicyclo[2.2.1]heptadienes by tandem intermolecular radical addition - Homoallylic radical rearrangement",

abstract = "Addition of thiols to 7-azabicyclo[2.2.1]heptadienes such as 16 leads exclusively to 7-thio-substituted 2-azabicyclo[2.2.1]hept-5-enes 17 in good yields via tandem intermolecular radical addition - homoallylic radical rearrangement.",

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year = "2001",

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AU - Hodgson, D. M.

AU - Bebbington, M. W.P.

AU - Willis, P.

PY - 2001/5/21

Y1 - 2001/5/21

N2 - Addition of thiols to 7-azabicyclo[2.2.1]heptadienes such as 16 leads exclusively to 7-thio-substituted 2-azabicyclo[2.2.1]hept-5-enes 17 in good yields via tandem intermolecular radical addition - homoallylic radical rearrangement.

AB - Addition of thiols to 7-azabicyclo[2.2.1]heptadienes such as 16 leads exclusively to 7-thio-substituted 2-azabicyclo[2.2.1]hept-5-enes 17 in good yields via tandem intermolecular radical addition - homoallylic radical rearrangement.

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DO - 10.1039/b101984h

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SP - 889

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JO - Chemical Communications

JF - Chemical Communications

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ER -

2-Azabicyclo[2.2.1]hept-5-enes from 7-azabicyclo[2.2.1]heptadienes by tandem intermolecular radical addition - Homoallylic radical rearrangement

Abstract

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