A 1,1′-ferrocenyl phosphine-borane: Synthesis, structure and evaluation in Rh-catalyzed hydroformylation

Magnus W.P. Bebbington, Sébastien Bontemps, Ghenwa Bouhadir, Martin J. Hanton, Robert P. Tooze, Hendrick Van Rensburg, Didier Bourissou

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39 Scopus citations

Abstract

The new ambiphilic ligand Ph2P-(1,1′-ferrocenyl)-BMes 2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.

Original languageEnglish
Pages (from-to)1556-1559
Number of pages4
JournalNew Journal of Chemistry
Volume34
Issue number8
DOIs
StatePublished - 1 Aug 2010

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    Bebbington, M. W. P., Bontemps, S., Bouhadir, G., Hanton, M. J., Tooze, R. P., Van Rensburg, H., & Bourissou, D. (2010). A 1,1′-ferrocenyl phosphine-borane: Synthesis, structure and evaluation in Rh-catalyzed hydroformylation. New Journal of Chemistry, 34(8), 1556-1559. https://doi.org/10.1039/c0nj00117a