TY - JOUR
T1 - A 1,1′-ferrocenyl phosphine-borane
T2 - Synthesis, structure and evaluation in Rh-catalyzed hydroformylation
AU - Bebbington, Magnus W.P.
AU - Bontemps, Sébastien
AU - Bouhadir, Ghenwa
AU - Hanton, Martin J.
AU - Tooze, Robert P.
AU - Van Rensburg, Hendrick
AU - Bourissou, Didier
PY - 2010/8
Y1 - 2010/8
N2 - The new ambiphilic ligand Ph2P-(1,1′-ferrocenyl)-BMes 2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.
AB - The new ambiphilic ligand Ph2P-(1,1′-ferrocenyl)-BMes 2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.
UR - http://www.scopus.com/inward/record.url?scp=77955074093&partnerID=8YFLogxK
U2 - 10.1039/c0nj00117a
DO - 10.1039/c0nj00117a
M3 - Article
AN - SCOPUS:77955074093
SN - 1144-0546
VL - 34
SP - 1556
EP - 1559
JO - New Journal of Chemistry
JF - New Journal of Chemistry
IS - 8
ER -