A 1,1′-ferrocenyl phosphine-borane: Synthesis, structure and evaluation in Rh-catalyzed hydroformylation

Magnus Bebbington, Sébastien Bontemps, Ghenwa Bouhadir, Martin J. Hanton, Robert P. Tooze, Hendrick Van Rensburg, Didier Bourissou

Research output: Contribution to journalArticle

38 Citations (Scopus)

Abstract

The new ambiphilic ligand Ph2P-(1,1′-ferrocenyl)-BMes 2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.

Original languageEnglish
Pages (from-to)1556-1559
Number of pages4
JournalNew Journal of Chemistry
Volume34
Issue number8
DOIs
StatePublished - 1 Aug 2010

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phosphine
Boranes
Hydroformylation
Ligands

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Bebbington, M., Bontemps, S., Bouhadir, G., Hanton, M. J., Tooze, R. P., Van Rensburg, H., & Bourissou, D. (2010). A 1,1′-ferrocenyl phosphine-borane: Synthesis, structure and evaluation in Rh-catalyzed hydroformylation. New Journal of Chemistry, 34(8), 1556-1559. https://doi.org/10.1039/c0nj00117a
Bebbington, Magnus ; Bontemps, Sébastien ; Bouhadir, Ghenwa ; Hanton, Martin J. ; Tooze, Robert P. ; Van Rensburg, Hendrick ; Bourissou, Didier. / A 1,1′-ferrocenyl phosphine-borane : Synthesis, structure and evaluation in Rh-catalyzed hydroformylation. In: New Journal of Chemistry. 2010 ; Vol. 34, No. 8. pp. 1556-1559.
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Bebbington, M, Bontemps, S, Bouhadir, G, Hanton, MJ, Tooze, RP, Van Rensburg, H & Bourissou, D 2010, 'A 1,1′-ferrocenyl phosphine-borane: Synthesis, structure and evaluation in Rh-catalyzed hydroformylation', New Journal of Chemistry, vol. 34, no. 8, pp. 1556-1559. https://doi.org/10.1039/c0nj00117a

A 1,1′-ferrocenyl phosphine-borane : Synthesis, structure and evaluation in Rh-catalyzed hydroformylation. / Bebbington, Magnus; Bontemps, Sébastien; Bouhadir, Ghenwa; Hanton, Martin J.; Tooze, Robert P.; Van Rensburg, Hendrick; Bourissou, Didier.

In: New Journal of Chemistry, Vol. 34, No. 8, 01.08.2010, p. 1556-1559.

Research output: Contribution to journalArticle

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