A 1,1′-ferrocenyl phosphine-borane: Synthesis, structure and evaluation in Rh-catalyzed hydroformylation

Magnus W.P. Bebbington; Sébastien Bontemps; Ghenwa Bouhadir; Martin J. Hanton; Robert P. Tooze; Hendrick Van Rensburg; Didier Bourissou

doi:10.1039/c0nj00117a

A 1,1′-ferrocenyl phosphine-borane: Synthesis, structure and evaluation in Rh-catalyzed hydroformylation

Magnus W.P. Bebbington
, Sébastien Bontemps
, Ghenwa Bouhadir
, Martin J. Hanton
, Robert P. Tooze
, Hendrick Van Rensburg
, Didier Bourissou

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

The new ambiphilic ligand Ph₂P-(1,1′-ferrocenyl)-BMes ₂, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.

Original language	English
Pages (from-to)	1556-1559
Number of pages	4
Journal	New Journal of Chemistry
Volume	34
Issue number	8
DOIs	https://doi.org/10.1039/c0nj00117a
State	Published - Aug 2010

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abstract = "The new ambiphilic ligand Ph2P-(1,1′-ferrocenyl)-BMes 2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.",

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doi = "10.1039/c0nj00117a",

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publisher = "Royal Society of Chemistry",

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T2 - Synthesis, structure and evaluation in Rh-catalyzed hydroformylation

AU - Bebbington, Magnus W.P.

AU - Bontemps, Sébastien

AU - Bouhadir, Ghenwa

AU - Hanton, Martin J.

AU - Tooze, Robert P.

AU - Van Rensburg, Hendrick

AU - Bourissou, Didier

PY - 2010/8

Y1 - 2010/8

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AB - The new ambiphilic ligand Ph2P-(1,1′-ferrocenyl)-BMes 2, prepared by sequential lithiation/electrophilic trapping of 1,1′-dibromoferrocene, adopts a monomeric structure free of dative P → B and Fe → B interactions. This flexible phosphine-borane and the related o-phenylene bridged system have been evaluated in Rh-catalyzed hydroformylation.

UR - https://www.scopus.com/pages/publications/77955074093

U2 - 10.1039/c0nj00117a

DO - 10.1039/c0nj00117a

M3 - Article

AN - SCOPUS:77955074093

SN - 1144-0546

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SP - 1556

EP - 1559

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 8

ER -

A 1,1′-ferrocenyl phosphine-borane: Synthesis, structure and evaluation in Rh-catalyzed hydroformylation

Abstract

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