Amino terminated polyethylene glycol functionalized graphene and its water solubility

Shifeng Hou, Robert D. Cuellari, Najeeb Hoshang H. Hakimi, Krutika Patel, Pratik Shah, Matthew Gorring, Stefanie Brachfeld

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

A chemical modification process was developed to functionalize graphene with specific groups. Graphene oxide (GO) was successfully functionalized with thionyl bromide which can be used as precursors for further functionalization. Amino terminated-polyethylene glycol (PEG-NH2) molecules were linked to single-layer graphene sheets through covalent bond. FT-IR, SEM and UV-vis spectroscopy techniques were used to characterize PEG modified graphene oxide and PEG modified reduced graphene oxide (PEG-RG). PEG-RG could disperse in water, tetrahydrofuran and ethylene glycol, with individual, single-layer graphene sheets spontaneously. The dispersion behavior of PEG-RG in an aqueous solvent has been investigated. A series of solutions of PEG-RG with concentrations of 0.001% to 1.5% were prepared and the PEG-RG dispersions exhibited long-term stability. In addition, a PEG-RG film with layered structure and high conductivity has been successfully prepared by filtration.

Original languageEnglish
Title of host publicationLarge-Area Electronics from Carbon Nanotubes, Graphene, and Related Noncarbon Nanostructures
Pages13-19
Number of pages7
Volume1205
StatePublished - 1 Dec 2010
Event2009 MRS Fall Meeting - Boston, MA, United States
Duration: 30 Nov 20094 Dec 2009

Other

Other2009 MRS Fall Meeting
CountryUnited States
CityBoston, MA
Period30/11/094/12/09

Fingerprint

Graphite
Graphene
Polyethylene glycols
glycols
polyethylenes
graphene
solubility
Solubility
Water
water
Oxides
oxides
covalent bonds
tetrahydrofuran
bromides
ethylene
Covalent bonds
Ethylene Glycol
Chemical modification
Ultraviolet spectroscopy

Cite this

Hou, S., Cuellari, R. D., Hakimi, N. H. H., Patel, K., Shah, P., Gorring, M., & Brachfeld, S. (2010). Amino terminated polyethylene glycol functionalized graphene and its water solubility. In Large-Area Electronics from Carbon Nanotubes, Graphene, and Related Noncarbon Nanostructures (Vol. 1205, pp. 13-19)
Hou, Shifeng ; Cuellari, Robert D. ; Hakimi, Najeeb Hoshang H. ; Patel, Krutika ; Shah, Pratik ; Gorring, Matthew ; Brachfeld, Stefanie. / Amino terminated polyethylene glycol functionalized graphene and its water solubility. Large-Area Electronics from Carbon Nanotubes, Graphene, and Related Noncarbon Nanostructures. Vol. 1205 2010. pp. 13-19
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abstract = "A chemical modification process was developed to functionalize graphene with specific groups. Graphene oxide (GO) was successfully functionalized with thionyl bromide which can be used as precursors for further functionalization. Amino terminated-polyethylene glycol (PEG-NH2) molecules were linked to single-layer graphene sheets through covalent bond. FT-IR, SEM and UV-vis spectroscopy techniques were used to characterize PEG modified graphene oxide and PEG modified reduced graphene oxide (PEG-RG). PEG-RG could disperse in water, tetrahydrofuran and ethylene glycol, with individual, single-layer graphene sheets spontaneously. The dispersion behavior of PEG-RG in an aqueous solvent has been investigated. A series of solutions of PEG-RG with concentrations of 0.001{\%} to 1.5{\%} were prepared and the PEG-RG dispersions exhibited long-term stability. In addition, a PEG-RG film with layered structure and high conductivity has been successfully prepared by filtration.",
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Hou, S, Cuellari, RD, Hakimi, NHH, Patel, K, Shah, P, Gorring, M & Brachfeld, S 2010, Amino terminated polyethylene glycol functionalized graphene and its water solubility. in Large-Area Electronics from Carbon Nanotubes, Graphene, and Related Noncarbon Nanostructures. vol. 1205, pp. 13-19, 2009 MRS Fall Meeting, Boston, MA, United States, 30/11/09.

Amino terminated polyethylene glycol functionalized graphene and its water solubility. / Hou, Shifeng; Cuellari, Robert D.; Hakimi, Najeeb Hoshang H.; Patel, Krutika; Shah, Pratik; Gorring, Matthew; Brachfeld, Stefanie.

Large-Area Electronics from Carbon Nanotubes, Graphene, and Related Noncarbon Nanostructures. Vol. 1205 2010. p. 13-19.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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T1 - Amino terminated polyethylene glycol functionalized graphene and its water solubility

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AU - Cuellari, Robert D.

AU - Hakimi, Najeeb Hoshang H.

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AU - Gorring, Matthew

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AB - A chemical modification process was developed to functionalize graphene with specific groups. Graphene oxide (GO) was successfully functionalized with thionyl bromide which can be used as precursors for further functionalization. Amino terminated-polyethylene glycol (PEG-NH2) molecules were linked to single-layer graphene sheets through covalent bond. FT-IR, SEM and UV-vis spectroscopy techniques were used to characterize PEG modified graphene oxide and PEG modified reduced graphene oxide (PEG-RG). PEG-RG could disperse in water, tetrahydrofuran and ethylene glycol, with individual, single-layer graphene sheets spontaneously. The dispersion behavior of PEG-RG in an aqueous solvent has been investigated. A series of solutions of PEG-RG with concentrations of 0.001% to 1.5% were prepared and the PEG-RG dispersions exhibited long-term stability. In addition, a PEG-RG film with layered structure and high conductivity has been successfully prepared by filtration.

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Hou S, Cuellari RD, Hakimi NHH, Patel K, Shah P, Gorring M et al. Amino terminated polyethylene glycol functionalized graphene and its water solubility. In Large-Area Electronics from Carbon Nanotubes, Graphene, and Related Noncarbon Nanostructures. Vol. 1205. 2010. p. 13-19