Characterization and Selective Removal of Organic Sulfur from Illinois Basin Coals

Stephen R. Palmer, Michael Kruge, John C. Crelling

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

In order to develop appropriate desulfurization strategies, the organic sulfur species and their distribution in coal need to be characterized. Peroxyacetic acid oxidation has been developed to render coal soluble, allowing for the subsequent GC-FID/FPD and GC-MS analysis of sulfur compounds. Four Illinois Basin coals and samples of sporinite, vitrinite and semifusinite isolated from them have been examined. Between 20 and 50% of the organic sulfur in these coals is associated with relatively few compounds detected in the volatile oxidation products. Of these, methylsulfonic acid is the most abundant, which, from model compound studies, results from oxidation of either methyl disulfide or simple thiophene structures in the coals. Although the species detected are commonly occurring among the majority of the coal and maceral fractions, their distribution varies considerably from sample to sample. By fractionating the oxidation products, a fraction was obtained that had a sulfur content of 18%. This fraction represents nearly 50% of the total organic sulfur but only 10% of the weight of the coal. Using peroxyacetic acid to desulfurize coal, it has been demonstrated that all pyrite and sulfate can be removed at room temperature and at least 25% of the organic sulfur at slightly higher temperatures.

Original languageEnglish
Pages (from-to)93-106
Number of pages14
JournalCoal Preparation
Volume10
Issue number1-4
DOIs
StatePublished - 1 Jan 1992

Fingerprint

Sulfur
sulfur
Coal
coal
basin
oxidation
Oxidation
Acids
acid
maceral
vitrinite
Sulfur compounds
removal
Pyrites
sulfur compound
Thiophene
Desulfurization
pyrite
sulfate
Temperature

Keywords

  • Characterization
  • Desulfurization
  • Macerals
  • Organic sulfur
  • Oxidation

Cite this

Palmer, Stephen R. ; Kruge, Michael ; Crelling, John C. / Characterization and Selective Removal of Organic Sulfur from Illinois Basin Coals. In: Coal Preparation. 1992 ; Vol. 10, No. 1-4. pp. 93-106.
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abstract = "In order to develop appropriate desulfurization strategies, the organic sulfur species and their distribution in coal need to be characterized. Peroxyacetic acid oxidation has been developed to render coal soluble, allowing for the subsequent GC-FID/FPD and GC-MS analysis of sulfur compounds. Four Illinois Basin coals and samples of sporinite, vitrinite and semifusinite isolated from them have been examined. Between 20 and 50{\%} of the organic sulfur in these coals is associated with relatively few compounds detected in the volatile oxidation products. Of these, methylsulfonic acid is the most abundant, which, from model compound studies, results from oxidation of either methyl disulfide or simple thiophene structures in the coals. Although the species detected are commonly occurring among the majority of the coal and maceral fractions, their distribution varies considerably from sample to sample. By fractionating the oxidation products, a fraction was obtained that had a sulfur content of 18{\%}. This fraction represents nearly 50{\%} of the total organic sulfur but only 10{\%} of the weight of the coal. Using peroxyacetic acid to desulfurize coal, it has been demonstrated that all pyrite and sulfate can be removed at room temperature and at least 25{\%} of the organic sulfur at slightly higher temperatures.",
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Characterization and Selective Removal of Organic Sulfur from Illinois Basin Coals. / Palmer, Stephen R.; Kruge, Michael; Crelling, John C.

In: Coal Preparation, Vol. 10, No. 1-4, 01.01.1992, p. 93-106.

Research output: Contribution to journalArticle

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