Desorption of bisphenol-A (BPA) and regeneration of BPA-spent granular activated carbon using ultrasonic irradiation and organic solvent extraction

Chao Zhou, Naiyun Gao, Ruoyu Li, Yang Deng

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Abstract: Desorption of bisphenol-A (BPA) from granular activated carbon (GAC) by ultrapure water and regeneration of BPA-spent GAC using ultrasonic irradiation and organic solvent extraction are investigated in this paper. The results showed that the pseudo-second-order kinetic model more appropriately described the BPA desorption pattern, and BPA desorption well followed the classical Arrhenius equation at a temperature range of 288–308 K with an activation energy of −56.47 kJ mol−1. Desorption rates of BPA were significantly favored by increasing acoustic intensity within a range of 17–100 W at 20 kHz frequency. Certain fraction of methanol or ethanol, particularly methanol, in the extraction solution enhanced the BPA desorption from the spent GAC. The optimal volumetric fraction of methanol in the extraction solution was 75% at which 80% of BPA on the spent GAC was desorbed within 400 min. A synergetic enhancement could be observed when ultrasonic irradiation was coupled with methanol for the GAC regeneration, and the regeneration efficiency was improved with the increasing irradiation intensity. Results demonstrate that the proposed ultrasonic irradiation and organic solvent extraction technology is a promising alternative to regenerate the spent GAC with BPA.

Original languageEnglish
Pages (from-to)3106-3113
Number of pages8
JournalDesalination and Water Treatment
Volume54
Issue number11
DOIs
StatePublished - 12 Jun 2015

Fingerprint

Solvent extraction
Activated carbon
Organic solvents
activated carbon
Desorption
desorption
irradiation
regeneration
Ultrasonics
Irradiation
methanol
Methanol
Acoustic intensity
activation energy
organic solvent
ethanol
Ethanol
acoustics
Activation energy
kinetics

Keywords

  • Bisphenol-A (BPA)
  • Granular activated carbon (GAC)
  • Organic solvent
  • Regeneration
  • Ultrasonic irradiation

Cite this

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title = "Desorption of bisphenol-A (BPA) and regeneration of BPA-spent granular activated carbon using ultrasonic irradiation and organic solvent extraction",
abstract = "Abstract: Desorption of bisphenol-A (BPA) from granular activated carbon (GAC) by ultrapure water and regeneration of BPA-spent GAC using ultrasonic irradiation and organic solvent extraction are investigated in this paper. The results showed that the pseudo-second-order kinetic model more appropriately described the BPA desorption pattern, and BPA desorption well followed the classical Arrhenius equation at a temperature range of 288–308 K with an activation energy of −56.47 kJ mol−1. Desorption rates of BPA were significantly favored by increasing acoustic intensity within a range of 17–100 W at 20 kHz frequency. Certain fraction of methanol or ethanol, particularly methanol, in the extraction solution enhanced the BPA desorption from the spent GAC. The optimal volumetric fraction of methanol in the extraction solution was 75{\%} at which 80{\%} of BPA on the spent GAC was desorbed within 400 min. A synergetic enhancement could be observed when ultrasonic irradiation was coupled with methanol for the GAC regeneration, and the regeneration efficiency was improved with the increasing irradiation intensity. Results demonstrate that the proposed ultrasonic irradiation and organic solvent extraction technology is a promising alternative to regenerate the spent GAC with BPA.",
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Desorption of bisphenol-A (BPA) and regeneration of BPA-spent granular activated carbon using ultrasonic irradiation and organic solvent extraction. / Zhou, Chao; Gao, Naiyun; Li, Ruoyu; Deng, Yang.

In: Desalination and Water Treatment, Vol. 54, No. 11, 12.06.2015, p. 3106-3113.

Research output: Contribution to journalArticle

TY - JOUR

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AU - Zhou, Chao

AU - Gao, Naiyun

AU - Li, Ruoyu

AU - Deng, Yang

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N2 - Abstract: Desorption of bisphenol-A (BPA) from granular activated carbon (GAC) by ultrapure water and regeneration of BPA-spent GAC using ultrasonic irradiation and organic solvent extraction are investigated in this paper. The results showed that the pseudo-second-order kinetic model more appropriately described the BPA desorption pattern, and BPA desorption well followed the classical Arrhenius equation at a temperature range of 288–308 K with an activation energy of −56.47 kJ mol−1. Desorption rates of BPA were significantly favored by increasing acoustic intensity within a range of 17–100 W at 20 kHz frequency. Certain fraction of methanol or ethanol, particularly methanol, in the extraction solution enhanced the BPA desorption from the spent GAC. The optimal volumetric fraction of methanol in the extraction solution was 75% at which 80% of BPA on the spent GAC was desorbed within 400 min. A synergetic enhancement could be observed when ultrasonic irradiation was coupled with methanol for the GAC regeneration, and the regeneration efficiency was improved with the increasing irradiation intensity. Results demonstrate that the proposed ultrasonic irradiation and organic solvent extraction technology is a promising alternative to regenerate the spent GAC with BPA.

AB - Abstract: Desorption of bisphenol-A (BPA) from granular activated carbon (GAC) by ultrapure water and regeneration of BPA-spent GAC using ultrasonic irradiation and organic solvent extraction are investigated in this paper. The results showed that the pseudo-second-order kinetic model more appropriately described the BPA desorption pattern, and BPA desorption well followed the classical Arrhenius equation at a temperature range of 288–308 K with an activation energy of −56.47 kJ mol−1. Desorption rates of BPA were significantly favored by increasing acoustic intensity within a range of 17–100 W at 20 kHz frequency. Certain fraction of methanol or ethanol, particularly methanol, in the extraction solution enhanced the BPA desorption from the spent GAC. The optimal volumetric fraction of methanol in the extraction solution was 75% at which 80% of BPA on the spent GAC was desorbed within 400 min. A synergetic enhancement could be observed when ultrasonic irradiation was coupled with methanol for the GAC regeneration, and the regeneration efficiency was improved with the increasing irradiation intensity. Results demonstrate that the proposed ultrasonic irradiation and organic solvent extraction technology is a promising alternative to regenerate the spent GAC with BPA.

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