Determination of residual triadimefon, triadimenol-a, triadimenol-b in corn by gel permeation chromatography and gas chromatography/mass spectrometry

Weiguo Zhang; Jinshan Gao; Shanshan Chen; Chongjiu Li

Determination of residual triadimefon, triadimenol-a, triadimenol-b in corn by gel permeation chromatography and gas chromatography/mass spectrometry

Weiguo Zhang, Jinshan Gao, Shanshan Chen, Chongjiu Li

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A method for simultaneous determination of triadimefon, triadimenol-a, triadimenol-b residues in corn is described. The pesticides were extracted using acetonitrile from sample. Most of lipids in co-extractives were removed by liquid-liquid extraction and gel permeation chromatography. Lutein was removed using solid-phase extraction on a Envi-carb column. The pesticides were finally determined by gas chromatography/mass spectrometry in selective-ion Monitor (SIM) simultaneously. The average recoveries (spiked level 0.05, 0.5 and 2 μg/g) were between 90% and 110%. The relative standard deviation of the method was less than 10% in every case.

Original language	English
Pages (from-to)	1442-1444
Number of pages	3
Journal	Fenxi Huaxue
Volume	33
Issue number	10
State	Published - Oct 2005

Keywords

Corn
Gas chromatography-mass spectrometry
Gel permeation chromatography
Triadimefon
Triadimenol-a
Triadimenol-b

Cite this

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title = "Determination of residual triadimefon, triadimenol-a, triadimenol-b in corn by gel permeation chromatography and gas chromatography/mass spectrometry",

abstract = "A method for simultaneous determination of triadimefon, triadimenol-a, triadimenol-b residues in corn is described. The pesticides were extracted using acetonitrile from sample. Most of lipids in co-extractives were removed by liquid-liquid extraction and gel permeation chromatography. Lutein was removed using solid-phase extraction on a Envi-carb column. The pesticides were finally determined by gas chromatography/mass spectrometry in selective-ion Monitor (SIM) simultaneously. The average recoveries (spiked level 0.05, 0.5 and 2 μg/g) were between 90% and 110%. The relative standard deviation of the method was less than 10% in every case.",

keywords = "Corn, Gas chromatography-mass spectrometry, Gel permeation chromatography, Triadimefon, Triadimenol-a, Triadimenol-b",

author = "Weiguo Zhang and Jinshan Gao and Shanshan Chen and Chongjiu Li",

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language = "English",

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journal = "Fenxi Huaxue",

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T1 - Determination of residual triadimefon, triadimenol-a, triadimenol-b in corn by gel permeation chromatography and gas chromatography/mass spectrometry

AU - Zhang, Weiguo

AU - Gao, Jinshan

AU - Chen, Shanshan

AU - Li, Chongjiu

PY - 2005/10

Y1 - 2005/10

N2 - A method for simultaneous determination of triadimefon, triadimenol-a, triadimenol-b residues in corn is described. The pesticides were extracted using acetonitrile from sample. Most of lipids in co-extractives were removed by liquid-liquid extraction and gel permeation chromatography. Lutein was removed using solid-phase extraction on a Envi-carb column. The pesticides were finally determined by gas chromatography/mass spectrometry in selective-ion Monitor (SIM) simultaneously. The average recoveries (spiked level 0.05, 0.5 and 2 μg/g) were between 90% and 110%. The relative standard deviation of the method was less than 10% in every case.

AB - A method for simultaneous determination of triadimefon, triadimenol-a, triadimenol-b residues in corn is described. The pesticides were extracted using acetonitrile from sample. Most of lipids in co-extractives were removed by liquid-liquid extraction and gel permeation chromatography. Lutein was removed using solid-phase extraction on a Envi-carb column. The pesticides were finally determined by gas chromatography/mass spectrometry in selective-ion Monitor (SIM) simultaneously. The average recoveries (spiked level 0.05, 0.5 and 2 μg/g) were between 90% and 110%. The relative standard deviation of the method was less than 10% in every case.

KW - Corn

KW - Gas chromatography-mass spectrometry

KW - Gel permeation chromatography

KW - Triadimefon

KW - Triadimenol-a

KW - Triadimenol-b

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M3 - Article

AN - SCOPUS:27744542730

SN - 0253-3820

VL - 33

SP - 1442

EP - 1444

JO - Fenxi Huaxue

JF - Fenxi Huaxue

IS - 10

ER -

Determination of residual triadimefon, triadimenol-a, triadimenol-b in corn by gel permeation chromatography and gas chromatography/mass spectrometry

Abstract

Keywords

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