Efficient soluble polymer-supported tartrate/Ti catalyst for asymmetric oxidation of prochiral sulfides

Jinshan Gao; Hongchao Guo; Shangzhong Liu; Min Wang

doi:10.1016/j.tetlet.2007.09.169

Efficient soluble polymer-supported tartrate/Ti catalyst for asymmetric oxidation of prochiral sulfides

Jinshan Gao, Hongchao Guo, Shangzhong Liu, Min Wang

Chemistry and Biochemistry

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26 Scopus citations

Abstract

A group of soluble polymer-supported chiral tartrate ligands was prepared by liquid-phase synthesis with ligand diversity strategy. Moderate to excellent chemical yields and enantiomeric excesses were obtained by using soluble polymer-supported tartrate ester in asymmetric oxidation of prochiral sulfides using Ti(O-i-Pr)₄/cumyl hydroperoxide, and the workup was greatly simplified. The influence of substituent in chiral tartrate ligands on the enantioselectivities of the reaction was disclosed.

Original language	English
Pages (from-to)	8453-8455
Number of pages	3
Journal	Tetrahedron Letters
Volume	48
Issue number	48
DOIs	https://doi.org/10.1016/j.tetlet.2007.09.169
State	Published - 26 Nov 2007

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10.1016/j.tetlet.2007.09.169

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title = "Efficient soluble polymer-supported tartrate/Ti catalyst for asymmetric oxidation of prochiral sulfides",

abstract = "A group of soluble polymer-supported chiral tartrate ligands was prepared by liquid-phase synthesis with ligand diversity strategy. Moderate to excellent chemical yields and enantiomeric excesses were obtained by using soluble polymer-supported tartrate ester in asymmetric oxidation of prochiral sulfides using Ti(O-i-Pr)4/cumyl hydroperoxide, and the workup was greatly simplified. The influence of substituent in chiral tartrate ligands on the enantioselectivities of the reaction was disclosed.",

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T1 - Efficient soluble polymer-supported tartrate/Ti catalyst for asymmetric oxidation of prochiral sulfides

AU - Gao, Jinshan

AU - Guo, Hongchao

AU - Liu, Shangzhong

AU - Wang, Min

PY - 2007/11/26

Y1 - 2007/11/26

N2 - A group of soluble polymer-supported chiral tartrate ligands was prepared by liquid-phase synthesis with ligand diversity strategy. Moderate to excellent chemical yields and enantiomeric excesses were obtained by using soluble polymer-supported tartrate ester in asymmetric oxidation of prochiral sulfides using Ti(O-i-Pr)4/cumyl hydroperoxide, and the workup was greatly simplified. The influence of substituent in chiral tartrate ligands on the enantioselectivities of the reaction was disclosed.

AB - A group of soluble polymer-supported chiral tartrate ligands was prepared by liquid-phase synthesis with ligand diversity strategy. Moderate to excellent chemical yields and enantiomeric excesses were obtained by using soluble polymer-supported tartrate ester in asymmetric oxidation of prochiral sulfides using Ti(O-i-Pr)4/cumyl hydroperoxide, and the workup was greatly simplified. The influence of substituent in chiral tartrate ligands on the enantioselectivities of the reaction was disclosed.

UR - https://www.scopus.com/pages/publications/35548999096

U2 - 10.1016/j.tetlet.2007.09.169

DO - 10.1016/j.tetlet.2007.09.169

M3 - Article

AN - SCOPUS:35548999096

SN - 0040-4039

VL - 48

SP - 8453

EP - 8455

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 48

ER -

Efficient soluble polymer-supported tartrate/Ti catalyst for asymmetric oxidation of prochiral sulfides

Abstract

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