Energy bands and final-state effects in K0.30MoO3

G. K. Wertheim; L. F. Schneemeyer; D. N.E. Buchanan

doi:10.1103/PhysRevB.32.3568

Energy bands and final-state effects in K0.30MoO3

G. K. Wertheim, L. F. Schneemeyer, D. N.E. Buchanan

Chemistry and Biochemistry

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Abstract

An x-ray photoemission spectroscopy study of the blue molybdenum bronze K0.30MoO3 shows a conduction band of Mo 4d character extending 2 eV below the Fermi level. The valence band lies between 2 and 10 eV. The Mo 3d core-electron spectrum has components at binding energies previously identified with Mo5+ and Mo6+ ions in related molybdenum oxide compounds. In this metallic system these two states are, however, of final-state origin, representing alternate screening channels and do not indicate that discrete valences are present in the initial state.

Original language	English
Pages (from-to)	3568-3572
Number of pages	5
Journal	Physical Review B
Volume	32
Issue number	6
DOIs	https://doi.org/10.1103/PhysRevB.32.3568
State	Published - 1985

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abstract = "An x-ray photoemission spectroscopy study of the blue molybdenum bronze K0.30MoO3 shows a conduction band of Mo 4d character extending 2 eV below the Fermi level. The valence band lies between 2 and 10 eV. The Mo 3d core-electron spectrum has components at binding energies previously identified with Mo5+ and Mo6+ ions in related molybdenum oxide compounds. In this metallic system these two states are, however, of final-state origin, representing alternate screening channels and do not indicate that discrete valences are present in the initial state.",

author = "Wertheim, {G. K.} and Schneemeyer, {L. F.} and Buchanan, {D. N.E.}",

year = "1985",

doi = "10.1103/PhysRevB.32.3568",

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journal = "Physical Review B",

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AU - Schneemeyer, L. F.

AU - Buchanan, D. N.E.

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Y1 - 1985

N2 - An x-ray photoemission spectroscopy study of the blue molybdenum bronze K0.30MoO3 shows a conduction band of Mo 4d character extending 2 eV below the Fermi level. The valence band lies between 2 and 10 eV. The Mo 3d core-electron spectrum has components at binding energies previously identified with Mo5+ and Mo6+ ions in related molybdenum oxide compounds. In this metallic system these two states are, however, of final-state origin, representing alternate screening channels and do not indicate that discrete valences are present in the initial state.

AB - An x-ray photoemission spectroscopy study of the blue molybdenum bronze K0.30MoO3 shows a conduction band of Mo 4d character extending 2 eV below the Fermi level. The valence band lies between 2 and 10 eV. The Mo 3d core-electron spectrum has components at binding energies previously identified with Mo5+ and Mo6+ ions in related molybdenum oxide compounds. In this metallic system these two states are, however, of final-state origin, representing alternate screening channels and do not indicate that discrete valences are present in the initial state.

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JO - Physical Review B

JF - Physical Review B

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ER -

Energy bands and final-state effects in K0.30MoO3

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