Gold(I)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination

Mari C.M. Higginbotham; Magnus W.P. Bebbington

doi:10.1039/c2cc33711h

Gold(I)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination

Mari C.M. Higginbotham, Magnus W.P. Bebbington

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Six-membered cyclic sulfamidates are prepared in high yields by treatment of allenic sulfamates with readily available gold(I) complexes. The reaction enables formation of N-substituted quaternary centres and complements existing processes for sulfamidate formation.

Original language	English
Pages (from-to)	7565-7567
Number of pages	3
Journal	Chemical Communications
Volume	48
Issue number	61
DOIs	https://doi.org/10.1039/c2cc33711h
State	Published - 4 Jul 2012

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title = "Gold(I)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination",

abstract = "Six-membered cyclic sulfamidates are prepared in high yields by treatment of allenic sulfamates with readily available gold(I) complexes. The reaction enables formation of N-substituted quaternary centres and complements existing processes for sulfamidate formation.",

author = "Higginbotham, {Mari C.M.} and Bebbington, {Magnus W.P.}",

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AU - Higginbotham, Mari C.M.

AU - Bebbington, Magnus W.P.

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Y1 - 2012/7/4

N2 - Six-membered cyclic sulfamidates are prepared in high yields by treatment of allenic sulfamates with readily available gold(I) complexes. The reaction enables formation of N-substituted quaternary centres and complements existing processes for sulfamidate formation.

AB - Six-membered cyclic sulfamidates are prepared in high yields by treatment of allenic sulfamates with readily available gold(I) complexes. The reaction enables formation of N-substituted quaternary centres and complements existing processes for sulfamidate formation.

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Gold(I)-catalysed synthesis of cyclic sulfamidates by intramolecular allene hydroamination

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