Ion-molecule reactions for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a tandem mass spectrometer

Mingkun Fu, Penggao Duan, Jinshan Gao, Hilkka I. Kenttämaa

Research output: Contribution to journalArticleResearchpeer-review

9 Citations (Scopus)

Abstract

A mass spectrometric method utilizing gas-phase ion-molecule reactions of 1-butanethiol and di-tert-butyl peroxide has been developed for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a FT-ICR mass spectrometer.

Original languageEnglish
Pages (from-to)5720-5722
Number of pages3
JournalAnalyst
Volume137
Issue number24
DOIs
StatePublished - 21 Dec 2012

Fingerprint

Mass spectrometers
Peroxides
Hydroxyl Radical
spectrometer
Gases
Ions
Molecules
ion
gas
n-butyl mercaptan
di-tert-butyl peroxide
method

Cite this

@article{d54f8fded7324df0b58721452bd68ca1,
title = "Ion-molecule reactions for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a tandem mass spectrometer",
abstract = "A mass spectrometric method utilizing gas-phase ion-molecule reactions of 1-butanethiol and di-tert-butyl peroxide has been developed for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a FT-ICR mass spectrometer.",
author = "Mingkun Fu and Penggao Duan and Jinshan Gao and Kentt{\"a}maa, {Hilkka I.}",
year = "2012",
month = "12",
day = "21",
doi = "10.1039/c2an35986c",
language = "English",
volume = "137",
pages = "5720--5722",
journal = "The Analyst",
issn = "0003-2654",
publisher = "Royal Society of Chemistry",
number = "24",

}

Ion-molecule reactions for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a tandem mass spectrometer. / Fu, Mingkun; Duan, Penggao; Gao, Jinshan; Kenttämaa, Hilkka I.

In: Analyst, Vol. 137, No. 24, 21.12.2012, p. 5720-5722.

Research output: Contribution to journalArticleResearchpeer-review

TY - JOUR

T1 - Ion-molecule reactions for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a tandem mass spectrometer

AU - Fu, Mingkun

AU - Duan, Penggao

AU - Gao, Jinshan

AU - Kenttämaa, Hilkka I.

PY - 2012/12/21

Y1 - 2012/12/21

N2 - A mass spectrometric method utilizing gas-phase ion-molecule reactions of 1-butanethiol and di-tert-butyl peroxide has been developed for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a FT-ICR mass spectrometer.

AB - A mass spectrometric method utilizing gas-phase ion-molecule reactions of 1-butanethiol and di-tert-butyl peroxide has been developed for the differentiation of primary, secondary and tertiary hydroxyl functionalities in protonated analytes in a FT-ICR mass spectrometer.

UR - http://www.scopus.com/inward/record.url?scp=84870485770&partnerID=8YFLogxK

U2 - 10.1039/c2an35986c

DO - 10.1039/c2an35986c

M3 - Article

VL - 137

SP - 5720

EP - 5722

JO - The Analyst

JF - The Analyst

SN - 0003-2654

IS - 24

ER -