Photoisomerizable heterodienes derived from a phosphine borane

Magnus W.P. Bebbington; Sébastien Bontemps; Ghenwa Bouhadir; Didier Bourissou

doi:10.1002/anie.200605078

Photoisomerizable heterodienes derived from a phosphine borane

Magnus W.P. Bebbington, Sébastien Bontemps, Ghenwa Bouhadir, Didier Bourissou

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

84 Scopus citations

Abstract

(Chemical Equation Presented) Stable relations: Reaction of phenylazide with a phosphine borane derivative gives rise to an intramolecularly stabilized phosphazide 1 (R = iPr, R′ = mesityl) that undergoes an unprecedented photoisomerization process associated with a change from an N _α→B to an N_β→B interaction (see scheme). The generality and possible reversibility of such phenomena are demonstrated with the related phosphazine adduct 2.

Original language	English
Pages (from-to)	3333-3336
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	46
Issue number	18
DOIs	https://doi.org/10.1002/anie.200605078
State	Published - 2007

Keywords

Boranes
Isomerization
Phosphazides
Phosphorus heterocycles
Photochemistry

Access to Document

10.1002/anie.200605078

Cite this

@article{fbf29960cbb54c329b248f6bfdd1368f,

title = "Photoisomerizable heterodienes derived from a phosphine borane",

abstract = "(Chemical Equation Presented) Stable relations: Reaction of phenylazide with a phosphine borane derivative gives rise to an intramolecularly stabilized phosphazide 1 (R = iPr, R′ = mesityl) that undergoes an unprecedented photoisomerization process associated with a change from an N α→B to an Nβ→B interaction (see scheme). The generality and possible reversibility of such phenomena are demonstrated with the related phosphazine adduct 2.",

keywords = "Boranes, Isomerization, Phosphazides, Phosphorus heterocycles, Photochemistry",

author = "Bebbington, {Magnus W.P.} and S{\'e}bastien Bontemps and Ghenwa Bouhadir and Didier Bourissou",

year = "2007",

doi = "10.1002/anie.200605078",

language = "English",

volume = "46",

pages = "3333--3336",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "18",

}

TY - JOUR

T1 - Photoisomerizable heterodienes derived from a phosphine borane

AU - Bebbington, Magnus W.P.

AU - Bontemps, Sébastien

AU - Bouhadir, Ghenwa

AU - Bourissou, Didier

PY - 2007

Y1 - 2007

N2 - (Chemical Equation Presented) Stable relations: Reaction of phenylazide with a phosphine borane derivative gives rise to an intramolecularly stabilized phosphazide 1 (R = iPr, R′ = mesityl) that undergoes an unprecedented photoisomerization process associated with a change from an N α→B to an Nβ→B interaction (see scheme). The generality and possible reversibility of such phenomena are demonstrated with the related phosphazine adduct 2.

AB - (Chemical Equation Presented) Stable relations: Reaction of phenylazide with a phosphine borane derivative gives rise to an intramolecularly stabilized phosphazide 1 (R = iPr, R′ = mesityl) that undergoes an unprecedented photoisomerization process associated with a change from an N α→B to an Nβ→B interaction (see scheme). The generality and possible reversibility of such phenomena are demonstrated with the related phosphazine adduct 2.

KW - Boranes

KW - Isomerization

KW - Phosphazides

KW - Phosphorus heterocycles

KW - Photochemistry

UR - http://www.scopus.com/inward/record.url?scp=34249996418&partnerID=8YFLogxK

U2 - 10.1002/anie.200605078

DO - 10.1002/anie.200605078

M3 - Article

C2 - 17378010

AN - SCOPUS:34249996418

SN - 1433-7851

VL - 46

SP - 3333

EP - 3336

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 18

ER -

Photoisomerizable heterodienes derived from a phosphine borane

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this