Platinum nanoparticles anchored on chelating group-modified graphene for methanol oxidation

Marzena S. Wietecha; Jun Zhu; Guihua Gao; Ning Wang; Huan Feng; Matthew L. Gorring; Marc L. Kasner; Shifeng Hou

doi:10.1016/j.jpowsour.2011.09.073

Platinum nanoparticles anchored on chelating group-modified graphene for methanol oxidation

Marzena S. Wietecha
, Jun Zhu
, Guihua Gao
, Ning Wang
, Huan Feng
, Matthew L. Gorring
, Marc L. Kasner
, Shifeng Hou

Research output: Contribution to journal › Article › peer-review

60 Scopus citations

Abstract

Platinum nanoparticles (Pt-NPs) were deposited onto N-(trimethoxy- silylpropyl) ethylenediamine triacetic acid (EDTA-silane) modified reduced graphene oxide (EDTA-RGO). The EDTA-RGO/Pt-NPs were coated onto a glass carbon electrode and characterized using scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman spectra, and electrochemical tests. The chelating groups create a micro-environment that is suitable for the catalytic behavior of Pt-NPs. Compared with traditional carbon-based Pt catalysts, EDTA-RGO/Pt-NPs exhibit great tolerance towards poisoning by CO.Graphene-supported Pt nanoparticles can be used for the fabrication of fuel cell electrodes and other catalytic devices.

Original language	English
Pages (from-to)	30-35
Number of pages	6
Journal	Journal of Power Sources
Volume	198
DOIs	https://doi.org/10.1016/j.jpowsour.2011.09.073
State	Published - 15 Jan 2012

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Electrochemical catalyst
Fuel cell
Graphene oxide
Methanol
Platinum nanoparticles

Access to Document

10.1016/j.jpowsour.2011.09.073

Cite this

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title = "Platinum nanoparticles anchored on chelating group-modified graphene for methanol oxidation",

abstract = "Platinum nanoparticles (Pt-NPs) were deposited onto N-(trimethoxy- silylpropyl) ethylenediamine triacetic acid (EDTA-silane) modified reduced graphene oxide (EDTA-RGO). The EDTA-RGO/Pt-NPs were coated onto a glass carbon electrode and characterized using scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman spectra, and electrochemical tests. The chelating groups create a micro-environment that is suitable for the catalytic behavior of Pt-NPs. Compared with traditional carbon-based Pt catalysts, EDTA-RGO/Pt-NPs exhibit great tolerance towards poisoning by CO.Graphene-supported Pt nanoparticles can be used for the fabrication of fuel cell electrodes and other catalytic devices.",

keywords = "Electrochemical catalyst, Fuel cell, Graphene oxide, Methanol, Platinum nanoparticles",

author = "Wietecha, \{Marzena S.\} and Jun Zhu and Guihua Gao and Ning Wang and Huan Feng and Gorring, \{Matthew L.\} and Kasner, \{Marc L.\} and Shifeng Hou",

year = "2012",

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day = "15",

doi = "10.1016/j.jpowsour.2011.09.073",

language = "English",

volume = "198",

pages = "30--35",

journal = "Journal of Power Sources",

issn = "0378-7753",

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TY - JOUR

T1 - Platinum nanoparticles anchored on chelating group-modified graphene for methanol oxidation

AU - Wietecha, Marzena S.

AU - Zhu, Jun

AU - Gao, Guihua

AU - Wang, Ning

AU - Feng, Huan

AU - Gorring, Matthew L.

AU - Kasner, Marc L.

AU - Hou, Shifeng

PY - 2012/1/15

Y1 - 2012/1/15

N2 - Platinum nanoparticles (Pt-NPs) were deposited onto N-(trimethoxy- silylpropyl) ethylenediamine triacetic acid (EDTA-silane) modified reduced graphene oxide (EDTA-RGO). The EDTA-RGO/Pt-NPs were coated onto a glass carbon electrode and characterized using scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman spectra, and electrochemical tests. The chelating groups create a micro-environment that is suitable for the catalytic behavior of Pt-NPs. Compared with traditional carbon-based Pt catalysts, EDTA-RGO/Pt-NPs exhibit great tolerance towards poisoning by CO.Graphene-supported Pt nanoparticles can be used for the fabrication of fuel cell electrodes and other catalytic devices.

AB - Platinum nanoparticles (Pt-NPs) were deposited onto N-(trimethoxy- silylpropyl) ethylenediamine triacetic acid (EDTA-silane) modified reduced graphene oxide (EDTA-RGO). The EDTA-RGO/Pt-NPs were coated onto a glass carbon electrode and characterized using scanning electron microscopy, transmission electron microscopy, X-ray diffraction, Raman spectra, and electrochemical tests. The chelating groups create a micro-environment that is suitable for the catalytic behavior of Pt-NPs. Compared with traditional carbon-based Pt catalysts, EDTA-RGO/Pt-NPs exhibit great tolerance towards poisoning by CO.Graphene-supported Pt nanoparticles can be used for the fabrication of fuel cell electrodes and other catalytic devices.

KW - Electrochemical catalyst

KW - Fuel cell

KW - Graphene oxide

KW - Methanol

KW - Platinum nanoparticles

UR - https://www.scopus.com/pages/publications/80755175371

U2 - 10.1016/j.jpowsour.2011.09.073

DO - 10.1016/j.jpowsour.2011.09.073

M3 - Article

AN - SCOPUS:80755175371

SN - 0378-7753

VL - 198

SP - 30

EP - 35

JO - Journal of Power Sources

JF - Journal of Power Sources

ER -

Platinum nanoparticles anchored on chelating group-modified graphene for methanol oxidation

Abstract

UN SDGs

Keywords

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