Preparation and properties of reduced bismuth and antimony molybdenum oxides

L. F. Schneemeyer; S. E. Spengler; F. J. DiSalvo; J. V. Waszczak

doi:10.1016/0025-5408(84)90114-4

Preparation and properties of reduced bismuth and antimony molybdenum oxides

L. F. Schneemeyer, S. E. Spengler, F. J. DiSalvo, J. V. Waszczak

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

From molybdenum trioxide-rich, low-melting eutectics formed in the MoO₃-Bi₂O₃ and MoO₃-Sb₂O₃ systems, large crystals of two new reduced bismuth molybdenum oxides and one antimony molybdenum oxide have been grown by the electrolytic reduction of molten salts. These phases are purple with high reflectivity, and show semiconducting behavior. All are orthorhombic with the same systematic absences (corresponding to space groups P_mma or P_mc2₁). Empirical formulas of these new oxides have the form M′_xMo₂O₅, with x = 0.22 or 0.27 dependent on growth conditions for the bismuth-containing compounds and with x = 0.47 for the anitmony-containing phase.

Original language	English
Pages (from-to)	525-529
Number of pages	5
Journal	Materials Research Bulletin
Volume	19
Issue number	4
DOIs	https://doi.org/10.1016/0025-5408(84)90114-4
State	Published - Apr 1984

Access to Document

10.1016/0025-5408(84)90114-4

Cite this

@article{a27cb2f427724b1cb76bd9664d76d307,

title = "Preparation and properties of reduced bismuth and antimony molybdenum oxides",

abstract = "From molybdenum trioxide-rich, low-melting eutectics formed in the MoO3-Bi2O3 and MoO3-Sb2O3 systems, large crystals of two new reduced bismuth molybdenum oxides and one antimony molybdenum oxide have been grown by the electrolytic reduction of molten salts. These phases are purple with high reflectivity, and show semiconducting behavior. All are orthorhombic with the same systematic absences (corresponding to space groups Pmma or Pmc21). Empirical formulas of these new oxides have the form M′xMo2O5, with x = 0.22 or 0.27 dependent on growth conditions for the bismuth-containing compounds and with x = 0.47 for the anitmony-containing phase.",

author = "Schneemeyer, {L. F.} and Spengler, {S. E.} and DiSalvo, {F. J.} and Waszczak, {J. V.}",

year = "1984",

month = apr,

doi = "10.1016/0025-5408(84)90114-4",

language = "English",

volume = "19",

pages = "525--529",

journal = "Materials Research Bulletin",

issn = "0025-5408",

publisher = "Elsevier Ltd",

number = "4",

}

TY - JOUR

T1 - Preparation and properties of reduced bismuth and antimony molybdenum oxides

AU - Schneemeyer, L. F.

AU - Spengler, S. E.

AU - DiSalvo, F. J.

AU - Waszczak, J. V.

PY - 1984/4

Y1 - 1984/4

N2 - From molybdenum trioxide-rich, low-melting eutectics formed in the MoO3-Bi2O3 and MoO3-Sb2O3 systems, large crystals of two new reduced bismuth molybdenum oxides and one antimony molybdenum oxide have been grown by the electrolytic reduction of molten salts. These phases are purple with high reflectivity, and show semiconducting behavior. All are orthorhombic with the same systematic absences (corresponding to space groups Pmma or Pmc21). Empirical formulas of these new oxides have the form M′xMo2O5, with x = 0.22 or 0.27 dependent on growth conditions for the bismuth-containing compounds and with x = 0.47 for the anitmony-containing phase.

AB - From molybdenum trioxide-rich, low-melting eutectics formed in the MoO3-Bi2O3 and MoO3-Sb2O3 systems, large crystals of two new reduced bismuth molybdenum oxides and one antimony molybdenum oxide have been grown by the electrolytic reduction of molten salts. These phases are purple with high reflectivity, and show semiconducting behavior. All are orthorhombic with the same systematic absences (corresponding to space groups Pmma or Pmc21). Empirical formulas of these new oxides have the form M′xMo2O5, with x = 0.22 or 0.27 dependent on growth conditions for the bismuth-containing compounds and with x = 0.47 for the anitmony-containing phase.

UR - http://www.scopus.com/inward/record.url?scp=0021411628&partnerID=8YFLogxK

U2 - 10.1016/0025-5408(84)90114-4

DO - 10.1016/0025-5408(84)90114-4

M3 - Article

AN - SCOPUS:0021411628

SN - 0025-5408

VL - 19

SP - 525

EP - 529

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 4

ER -

Preparation and properties of reduced bismuth and antimony molybdenum oxides

Abstract

Access to Document

Other files and links

Fingerprint

Cite this