Radical induced degradation of acetaminophen with Fe3O4 magnetic nanoparticles as heterogeneous activator of peroxymonosulfate

Chaoqun Tan, Naiyun Gao, Yang Deng, Jing Deng, Shiqing Zhou, Jun Li, Xiaoyan Xin

Research output: Contribution to journalArticlepeer-review

320 Scopus citations


Magnetic nano-scaled particles Fe3O4 were studied for the activation of peroxymonosulfate (PMS) to generate active radicals for degradation of acetaminophen (APAP) in water. The Fe3O4 MNPs were found to effectively catalyze PMS for removal of APAP, and the reactions well followed a pseudo-first-order kinetics pattern (R2>0.95). Within 120min, approximately 75% of 10ppm APAP was accomplished by 0.2mM PMS in the presence of 0.8g/L Fe3O4 MNPs with little Fe3+ leaching (<4μg/L). Higher Fe3O4 MNP dose, lower initial APAP concentration, neutral pH, and higher reaction temperature favored the APAP degradation. The production of sulfate radicals and hydroxyl radicals was validated through two ways: (1) indirectly from the scavenging tests with scavenging agents, tert-butyl alcohol (TBA) and ethanol (EtOH); (2) directly from the electron paramagnetic resonance (ESR) tests with 0.1M 5,5-dimethyl-1-pyrrolidine N-oxide (DMPO). Plausible mechanisms on the radical generation from Fe3O4 MNP activation of PMS are proposed based on the results of radical identification tests and XPS analysis. It appeared that Fe2+Fe3+ on the catalyst surface was responsible for the radical generation. The results demonstrated that Fe3O4 MNPs activated PMS is a promising technology for water pollution caused by contaminants such as pharmaceuticals.

Original languageEnglish
Pages (from-to)452-460
Number of pages9
JournalJournal of Hazardous Materials
StatePublished - 15 Jul 2014


  • Acetaminophen
  • Heterogeneous catalyst
  • Peroxymonosulfate
  • Radicals


Dive into the research topics of 'Radical induced degradation of acetaminophen with Fe<sub>3</sub>O<sub>4</sub> magnetic nanoparticles as heterogeneous activator of peroxymonosulfate'. Together they form a unique fingerprint.

Cite this