Substituent Effects on the Reactivity of the 2,4,6-Tridehydropyridinium Cation, an Aromatic σ,σ,σ-Triradical

Keyphrases

• Aromatics 100%
• Radical Reactions 100%
• Triradicals 100%
• Substituent Effect 100%
• Proton Transfer Reaction 100%
• Resonance Structures 100%
• Through-space Coupling 100%
• Hydroxyl Group 50%
• Low Energy 50%
• Proton Transfer 50%
• Gas Phase 50%
• Cyano 50%
• Electron-donating 50%
• Cyano-substituted 50%
• Monoradicals 50%
• Singlet State 50%
• Biradical 50%
• Acidity 50%
• Non-radical 50%
• Triplet State 50%
• Cyano Group 50%
• Electron-withdrawing 50%
• Cyano Substituent 50%
• Fast Protons 50%
• Barrier-free 50%
• Revealed Behavior 50%
• Vertical Electron Affinity 50%

Chemistry

• Proton Transfer 100%
• Substituent Effect 100%
• Transfer Reaction 66%
• Radical Reaction 66%
• Ground State 33%
• Electron Affinity 33%
• Hydroxyl Group 33%
• Cyano Group 33%
• Triplet State Energy 33%
• acidity 33%