The synthesis and cyclic voltammetry of select ferrocene piano-stool isocyanide complexes

Brian Humphrey, Raidiri E. Castilo, Amy H. Vega, Argelia Feliciano, Marjorie E. Squires

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Ferrocene piano-stool isocyanide complexes ([CpFeL3] +, Cp = η5-C5H5, L = tert-butyl isocyanide (1), cyclohexyl isocyanide (2), and 2,6-dimethylphenyl isocyanide (3)) are formed by chemical oxidation of ferrocene in the presence of a stoichiometric amount of isocyanide ligand (1:3). The complexes are characterized by elemental analysis, routine spectroscopic methods (IR, 1H NMR, 13C NMR, and UV-Vis), and cyclic voltammetry.

Original languageEnglish
Pages (from-to)271-274
Number of pages4
JournalInorganica Chimica Acta
Volume368
Issue number1
DOIs
StatePublished - 15 Mar 2011

Fingerprint

Cyanides
Cyclic voltammetry
Nuclear magnetic resonance
nuclear magnetic resonance
synthesis
Ligands
Oxidation
ligands
oxidation
Chemical analysis
ferrocene

Keywords

  • Cyclic voltammetry
  • Ferrocene piano-stool complex
  • Isocyanide ligand
  • Organometallic chemistry

Cite this

Humphrey, Brian ; Castilo, Raidiri E. ; Vega, Amy H. ; Feliciano, Argelia ; Squires, Marjorie E. / The synthesis and cyclic voltammetry of select ferrocene piano-stool isocyanide complexes. In: Inorganica Chimica Acta. 2011 ; Vol. 368, No. 1. pp. 271-274.
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The synthesis and cyclic voltammetry of select ferrocene piano-stool isocyanide complexes. / Humphrey, Brian; Castilo, Raidiri E.; Vega, Amy H.; Feliciano, Argelia; Squires, Marjorie E.

In: Inorganica Chimica Acta, Vol. 368, No. 1, 15.03.2011, p. 271-274.

Research output: Contribution to journalArticle

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AU - Castilo, Raidiri E.

AU - Vega, Amy H.

AU - Feliciano, Argelia

AU - Squires, Marjorie E.

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KW - Cyclic voltammetry

KW - Ferrocene piano-stool complex

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KW - Organometallic chemistry

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