TY - JOUR
T1 - The synthesis and cyclic voltammetry of select ferrocene piano-stool isocyanide complexes
AU - Humphrey, Brian D.
AU - Castilo, Raidiri E.
AU - Vega, Amy H.
AU - Feliciano, Argelia
AU - Squires, Marjorie E.
PY - 2011/3/15
Y1 - 2011/3/15
N2 - Ferrocene piano-stool isocyanide complexes ([CpFeL3] +, Cp = η5-C5H5, L = tert-butyl isocyanide (1), cyclohexyl isocyanide (2), and 2,6-dimethylphenyl isocyanide (3)) are formed by chemical oxidation of ferrocene in the presence of a stoichiometric amount of isocyanide ligand (1:3). The complexes are characterized by elemental analysis, routine spectroscopic methods (IR, 1H NMR, 13C NMR, and UV-Vis), and cyclic voltammetry.
AB - Ferrocene piano-stool isocyanide complexes ([CpFeL3] +, Cp = η5-C5H5, L = tert-butyl isocyanide (1), cyclohexyl isocyanide (2), and 2,6-dimethylphenyl isocyanide (3)) are formed by chemical oxidation of ferrocene in the presence of a stoichiometric amount of isocyanide ligand (1:3). The complexes are characterized by elemental analysis, routine spectroscopic methods (IR, 1H NMR, 13C NMR, and UV-Vis), and cyclic voltammetry.
KW - Cyclic voltammetry
KW - Ferrocene piano-stool complex
KW - Isocyanide ligand
KW - Organometallic chemistry
UR - http://www.scopus.com/inward/record.url?scp=79952009293&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2011.01.025
DO - 10.1016/j.ica.2011.01.025
M3 - Article
AN - SCOPUS:79952009293
SN - 0020-1693
VL - 368
SP - 271
EP - 274
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -