The synthesis and cyclic voltammetry of select ferrocene piano-stool isocyanide complexes

Brian D. Humphrey; Raidiri E. Castilo; Amy H. Vega; Argelia Feliciano; Marjorie E. Squires

doi:10.1016/j.ica.2011.01.025

The synthesis and cyclic voltammetry of select ferrocene piano-stool isocyanide complexes

Brian D. Humphrey
, Raidiri E. Castilo
, Amy H. Vega
, Argelia Feliciano
, Marjorie E. Squires

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Ferrocene piano-stool isocyanide complexes ([CpFeL₃] ⁺, Cp = η⁵-C₅H₅, L = tert-butyl isocyanide (1), cyclohexyl isocyanide (2), and 2,6-dimethylphenyl isocyanide (3)) are formed by chemical oxidation of ferrocene in the presence of a stoichiometric amount of isocyanide ligand (1:3). The complexes are characterized by elemental analysis, routine spectroscopic methods (IR, ¹H NMR, ¹³C NMR, and UV-Vis), and cyclic voltammetry.

Original language	English
Pages (from-to)	271-274
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	368
Issue number	1
DOIs	https://doi.org/10.1016/j.ica.2011.01.025
State	Published - 15 Mar 2011

Keywords

Cyclic voltammetry
Ferrocene piano-stool complex
Isocyanide ligand
Organometallic chemistry

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10.1016/j.ica.2011.01.025

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title = "The synthesis and cyclic voltammetry of select ferrocene piano-stool isocyanide complexes",

abstract = "Ferrocene piano-stool isocyanide complexes ([CpFeL3] +, Cp = η5-C5H5, L = tert-butyl isocyanide (1), cyclohexyl isocyanide (2), and 2,6-dimethylphenyl isocyanide (3)) are formed by chemical oxidation of ferrocene in the presence of a stoichiometric amount of isocyanide ligand (1:3). The complexes are characterized by elemental analysis, routine spectroscopic methods (IR, 1H NMR, 13C NMR, and UV-Vis), and cyclic voltammetry.",

keywords = "Cyclic voltammetry, Ferrocene piano-stool complex, Isocyanide ligand, Organometallic chemistry",

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year = "2011",

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doi = "10.1016/j.ica.2011.01.025",

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TY - JOUR

T1 - The synthesis and cyclic voltammetry of select ferrocene piano-stool isocyanide complexes

AU - Humphrey, Brian D.

AU - Castilo, Raidiri E.

AU - Vega, Amy H.

AU - Feliciano, Argelia

AU - Squires, Marjorie E.

PY - 2011/3/15

Y1 - 2011/3/15

N2 - Ferrocene piano-stool isocyanide complexes ([CpFeL3] +, Cp = η5-C5H5, L = tert-butyl isocyanide (1), cyclohexyl isocyanide (2), and 2,6-dimethylphenyl isocyanide (3)) are formed by chemical oxidation of ferrocene in the presence of a stoichiometric amount of isocyanide ligand (1:3). The complexes are characterized by elemental analysis, routine spectroscopic methods (IR, 1H NMR, 13C NMR, and UV-Vis), and cyclic voltammetry.

AB - Ferrocene piano-stool isocyanide complexes ([CpFeL3] +, Cp = η5-C5H5, L = tert-butyl isocyanide (1), cyclohexyl isocyanide (2), and 2,6-dimethylphenyl isocyanide (3)) are formed by chemical oxidation of ferrocene in the presence of a stoichiometric amount of isocyanide ligand (1:3). The complexes are characterized by elemental analysis, routine spectroscopic methods (IR, 1H NMR, 13C NMR, and UV-Vis), and cyclic voltammetry.

KW - Cyclic voltammetry

KW - Ferrocene piano-stool complex

KW - Isocyanide ligand

KW - Organometallic chemistry

UR - https://www.scopus.com/pages/publications/79952009293

U2 - 10.1016/j.ica.2011.01.025

DO - 10.1016/j.ica.2011.01.025

M3 - Article

AN - SCOPUS:79952009293

SN - 0020-1693

VL - 368

SP - 271

EP - 274

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

The synthesis and cyclic voltammetry of select ferrocene piano-stool isocyanide complexes

Abstract

Keywords

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